送交者: thatisit 2004年2月01日15:18:56 于 [教育与学术]
http://www.bbsland.com 近两年常常看到国内学者的论文发表在享誉世界的著名化学期刊德国《应用化学 国际版
》
(Angew. Chem. Int. Ed.)上，实感欣慰，也惊讶于国内学者的科研水平之突飞猛进。但
很遗憾
也屡屡发现有的论文在发表后不久，就登出道歉通知，或者是漏引了重要的参考文献，或
者是
研究内容被其他科学家质疑。浏览这两年的Angew. Chem. Int. Ed.发现，此类事件很不
常见但却
集中发生在中国化学家身上，不能不让人担忧中国化学研究的国际声誉是否会蒙受打击。
这两年通过众多杰出的中国化学家共同努力，国内化学研究的国际影响力不断提升，但这
样
的事件会让国际同行对中国学者的科研态度和学术道德，至少是每个科学家
应有的学术严谨性，产生怀疑。退一步讲，此类事件在同一杂志多次发生，恐怕对后人投
稿的
接受率会产生影响，毕竟再好的编辑也是人担任的，而且没有人会否认编辑的态度或心理
倾向对
投稿人的命运有很大的影响。 审稿人也不是万能的，他甚至不比作者本人更高明，这在
学术界
不是什么秘密。所以投稿人不能完全依赖审稿人来甄别自己工作的创新性
学术期刊刊登更正通知是常见的，但主要是数据、文字、地址等方面的更正，漏引参考文
献
这样的错误也不是没有，但像发表别人已经发表过的结果，却不得不道歉漏引了重要文献
，这种
自打耳光之错实在是太丢人了。刊登这样的更正，实际上等同于撤销论文。只不过外国人
勇于撤销
自己的论文，而国人却舍不得。
至于像中山大学Xu An-Wu（许安武？）那样被别人公开质疑发表研究内容的真实性，更是
滑天
下之大稽！Angew 偶尔也登Correspondence，主要是发表尖锐的学术争论。许教授的问题
看来不仅仅
是学术争论。一共9篇论文被别人同时质疑，实不多见。更严重的是，同样的质疑时隔一
年又被同一
作者在Chem. Mater. 16 (1), 195 -195, 2004 上再次发表，这次许教授的回应明显不理
直气壮了，而他
第一次在Angew 的回应中许诺近期将发表的类似的研究结果再也没发出来过。
一直以来就有人讨论国内科研的浮躁，看来不无道理。国内化学同行是不是压力太大，太
急功近利了？
几例道歉或质疑：
1。青岛科技大学建方方小组
Angew. Chem.Int. Ed. Volume 43, Issue 1, Pages 14
http://www3.interscience.wiley.com/cgi-bin/fulltext/106572213/HTMLSTART
Corrigendum
[Ni6(SCH2CH2OH)12]: A Double Crown [12]Metallacrown-6 Nickel(II) Cluster
Fang-Fang Jian, Prof. Dr. 1 *, Kui Jiao, Prof. Dr. 1, Yan Li 1, Pu-Su Zhao, D
r. 2, Lu-De Lu, Prof. Dr. 2
1New Materials & Function Coordination Chemistry Laboratory, Qingdao Universi
ty of Science and Technology, Qingdao, 266042, P.R. China, Fax: (+86) 532-402
3-606
2Materials Chemistry Laboratory, Nanjing University of Science and Technology
, Nanjing, 210094, P.R. China
email: Fang-Fang Jian (ffj2003@163169.net)
*Correspondence to Fang-Fang Jian, 1New Materials & Function Coordination Che
mistry Laboratory, Qingdao University of Science and Technology, Qingdao, 266
042, P.R.
China, Fax: (+86) 532-4023-606
This work was supported by the Natural Science Foundation of Shandong provinc
e (no. Y2002B06).
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Article Text
In the Communication [Ni6(SCH2CH2OH)12]: A Double Crown [12]Metallacrown-6 Ni
ckel(II) Cluster by F.-F. Jian, K. Jiao, Y. Li, P.-S. Zhao, L.-D. Lu[1] the c
rystal
structure of the main compound has already been reported: Nickel and Palladiu
m Complexes of 1-Hydroxyethane-2-thiol and Analogues. Part 1. Crystal Structu
re of
Cyclohexakis[bis-(-1-hydroxyethane-2-thiolato)-nickel(II)] R. O. Gould, M. M.
Harding, J. Chem. Soc. (A) 1970, 875-881. The authors also missed several im
portant
references to related species, these include: A New Type of Cyclic Transition
Metal Complex, [Ni(SC2H5)2]6 P. Woodward, L. F. Dahl, E. W. Abel, B. C. Cros
se, J. Am.
Chem. Soc. 1965, 87, 5251-5253; The Structure of a Toroidal, Neutral, Homolep
tic Ni(II) Complex with a Chelate Dithiolate Ligand, [Ni6(SCH2CH2CH2S)6] J. S
letten, J. A.
Kovacs, Acta Chem. Scand. 1994, 48, 929-932; Cyclo-[Ni(2-SPh)2]9 and Cyclo-[N
i(2-SPh)2]11: New Oligomeric Types of Toroidal Nickel(II) Thiolates Containin
g
Geometrically Unprecedented 9- and 11-Membered Ring Systems" S. A. Ivanov, M.
A. Kozee, W. Alex Merrill, S. Agarwal, L. F. Dahl J. Chem. Soc. Dalton Trans
. 2002,
4105-4115. The authors apologize for these oversights.
2。厦门大学郑兰荪小组
Angew. Chem.Int. Ed. Volume 42, Issue 19, Pages 2108
http://www3.interscience.wiley.com/cgi-bin/fulltext/104532556/HTMLSTART
Apology
In the Communication “Nanoporous Lanthanide–Copper(ii) Coordination
Polymers: Syntheses and Crystal Structures of
[{M2(Cu3(iminodiacetate)6)} · 8H2O]n
(M=La, Nd, Eu)” by Y.-P. Ren, L.-S. Long, et al. (Angew. Chem. 2003,
115, 550; Angew. Chem. Int. Ed. 2003, 42, 532) the authors missed
important references:
“Synthesis, Crystal Structure and Magnetic Properties of a Series of
Polymeric Lanthanoid–Copper Complexes
[Ln2Cu3{O(CH2CO2)2}6] · nH2O (Ln=La, Nd, n=9; Ln=Er, n=6)” (J. G. Mao,
J. S. Huang, J. F. Ma, J. Z. Ni, Trans. Met. Chem. 1997, 22, 277–280),
“Synthesis and Crystal Structure of a Novel Lanthanide–Copper Mixed
Metal Complex: Gd2Cu3{O(CH2COO)2}6 · 9H2O” (J. G.
Mao, L. Song, X. Y. Huang, J. S. Huang, Polyhedron 1997, 16, 963–966),
“Synthesis and Structural Characterization of a Novel Polymeric
Gadolinium(iii)–Copper(ii) Complex of Iminodiacetic Acid” (J. G.
Mao, L. Song, J. S. Huang, J. Chem. Crystallogr. 1998, 28, 475–479),
and “Synthesis and Crystal Structure of a New Praseodymiun(iii)–
Copper(ii) Polymeric Complex: [Pr2(Cu3(L1)6)n] (H2L1=NH{CH2COOH}2)”
(J. G. Mao, L Song, J. S. Huang, Chinese J. Struct. Chem.
1999, 18, 4–8).
The authors apologize for this oversight and thank Qinde Liu of Queen’s
University, Canada, and Prof. J. G. Mao, Fuzhou, China, for bringing it
to their attention.
3。复旦大学赵东元小组
1） Angew. Chem. Int. Ed. Volume 40, Issue 19, Pages 3503
http://www3.interscience.wiley.com/cgi-bin/fulltext/85514238/HTMLSTART
Corrigendum
A Large 24-Membered-Ring Germanate Zeolite-Type Open-Framework Structure with
Three-Dimensional Intersecting Channels
Yaming Zhou, Haoguo Zhu, Zhenxia Chen, Minqin Chen, Yan Xu, Haoyu Zhang, Dong
yuan Zhao, Prof. Dr. *
Department of Chemistry Fudan University Shanghai 200433 (P. R. China) Fax: (
+86) 21-65641740
email: Dongyuan Zhao (dyzhao@fudan.edu.cn)
*Correspondence to Dongyuan Zhao, Department of Chemistry Fudan University Sh
anghai 200433 (P. R. China) Fax: (+86) 21-65641740
This work was supported by the NSF of China (Grant No. 29873012 and 29925309)
, National Education Ministry, State Key Basic Research Program of PRC (G2000
048001)
Shanghai Science Foundation, and the Key Laboratory of Inorganic Hydrothermal
Synthesis, Jilin University. We thank Prof. S. Feng and Dr. Z. Shi for inval
uable discussions.
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Article Text
In the communication by D. Zhao and co-workers in Issue 11, 2001, pp. 2166-21
68, two relevant references were not cited, for which the authors apologize:
a) A. K.
Cheetham, G. Férey, T. Loiseau, Angew. Chem. 1999, 111, 3466-3492; Angew. Ch
em. Int. Ed. 1999, 38, 3268-3292; b) N. Guillou, Q. Gao, M. Nogues, R. E. Mor
ris, M.
Hervieu, G. Férey, A. K. Cheetham, C.R. Acad. Sci. Ser. IIc 1999, 2, 387-392
.
2) Ange. Chem. Int. Ed. Volume 41, Issue 13, Pages 2226
http://www3.interscience.wiley.com/cgi-bin/fulltext/95515430/HTMLSTART
此文虽然与发表在J. Am. Chem. Soc.的论文同时投出而不相互引用，显然有一稿两投之
嫌
Corrigendum
Strongly Acidic and High-Temperature Hydrothermally Stable Mesoporous Alumino
silicates with Ordered Hexagonal Structure
Zongtao Zhang, Dr. 1, Yu Han 1, Lei Zhu 1, Runwei Wang 1, Yi Yu 1, Shilun Qiu
, Prof. 1 *, Dongyuan Zhao, Prof. 2, Feng-Shou Xiao, Prof. 1 *
1Department of Chemistry Jilin University Changchun 130023 (China) Fax: (+86)
431-5671974
2Department of Chemistry Fudan University Shanghai 200433 (China)
email: Shilun Qiu (sqiu@mail.jlu.edu.cn) Feng-Shou Xiao (fsxiao@mail.jlu.edu.
cn)
*Correspondence to Shilun Qiu, 1Department of Chemistry Jilin University Chan
gchun 130023 (China) Fax: (+86) 431-5671974
*Correspondence to Feng-Shou Xiao, 1Department of Chemistry Jilin University
Changchun 130023 (China) Fax: (+86) 431-5671974
This work was supported by the National Natural Science Foundation of China (
No. 29825108), the State Basic Research Project, and the National Advanced Ma
terials
Committee of China. We thank Prof. Ruren Xu, Dr. Haiping Sun, Prof. Bensan Zo
u, Prof. Ze Zhang, and Professor Osamu Tarasaki for helpful suggestions, disc
ussions, and
transmission electron microscopy experiments.
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Article Text
In the Communication Strongly Acidic and High-Temperature Hydrothermally Stab
le Mesoporous Aluminosilicates with Ordered Hexagonal Structure (Z. Zhang, Y.
Han, L.
Zhu, R. Wang, Y. Yu, S. Qiu, D. Zhao, F.-S. Xiao, Angew. Chem. Int. Ed. 2001,
40, 1258-1362) the thematically related manuxxxx Mesoporous Aluminosilicates
with
Ordered Hexagonal Structure, Strong Acidity, and Extraordinary Hydrothermal S
tability at High Temperatures (Z. Zhang, Y. Han, F.-S. Xiao, S. Qiu, L. Zhu,
R. Wang, Y. Yu,
Z. Zhang, B. Zou, Y. Wang, H. Sun, D. Zhao, Y. Wei, J. Am. Chem. Soc. 2001, 1
23, 5014-5021) was not cited (and vice versa), although both manuxxxxs were x
xxxted to
the respective journals at the same time. The authors apologize for this mist
ake.
4. 中山大学许安武小组
1) Angew. Chem. Int. Ed. 2003， Volume 42, Issue 14, Pages 1572-1573
http://www3.interscience.wiley.com/cgi-bin/fulltext/104524461/HTMLSTART
Correspondence
Do Mesostructured Materials Have an Unusual Macrolamellar Structure?
Zhong-Yong Yuan, Dr. 1, Marie-France Six-Boulanger 2, Bao-Lian Su, Prof. 1 *
1Laboratory of Inorganic Materials Chemistry (CMI), Institute for Studies in
Interface Sciences (ISIS), The University of Namur (FUNDP), 61 rue de Bruxell
es, 5000 Namur,
Belgium, Fax: (+32) 81-725414
2Interfaculty Unit of Electron Microscopy, The University of Namur (FUNDP), 6
1 rue de Bruxelles, 5000 Namur, Belgium
email: Bao-Lian Su (bao-lian.su@fundp.ac.be)
*Correspondence to Bao-Lian Su, 1Laboratory of Inorganic Materials Chemistry
(CMI), Institute for Studies in Interface Sciences (ISIS), The University of
Namur (FUNDP),
61 rue de Bruxelles, 5000 Namur, Belgium, Fax: (+32) 81-725414
Angew. Chem. Int. Ed. Volume 42, Issue 14, Pages 1574-1575
Additional Proof for the Existence for Microlamellar Structured ZSU-L Templat
ed from Silicone Surfactants
An-Wu Xu, Prof. *
School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou
510275, China, Fax: (+86) 20-84111088
email: An-Wu Xu (cedc17@zsu.edu.cn)
*Correspondence to An-Wu Xu, School of Chemistry and Chemical Engineering, Zh
ongshan University, Guangzhou 510275, China, Fax: (+86) 20-84111088
2) Chem. Mater., 16 (1), 195 -195, 2004.
http://pubs.acs.org/cgi-bin/sample.cgi/cmatex/2004/16/i01/html/cm031023q.html
Comment on Spontaneously Ordered Sol-Gel Composites with Submicrometer Period
icity
Zhong-Yong Yuan and Bao-Lian Su*
Laboratory of Inorganic Materials Chemistry, I.S.I.S., The University of Namu
r (FUNDP), 61 rue de Bruxelles, B-5000 Namur, Belgium
Chem. Mater., 16 (1), 198 -198, 2004
Reply to the Comment on Spontaneously Ordered Sol-Gel Composites with Submicr
ometer Periodicity
An-Wu Xu
School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou
510275, China
许安武被质疑的9篇论文：
1. Xu, A. W. Chem. Mater. 2002, 14, 3625-3627.
2. Xu, A. W. J. Phys. Chem. B 2002, 106, 13161-13164.
3. Xu, A. W.; Cai, Y. P.; Zhang, H. X.; Zhang, L. Z.; Yu, J. C. Angew. Chem.
2002, 114, 4000-4004; Angew. Chem., Int. Ed. 2002, 41, 3844-3848.
4. Xu, A. W.; Yu, J. C.; Zhang, H. X.; Zhang, L. Z.; Kuang, D. B.; Fang, Y. P
. Langmuir 2002, 18, 9570-9573.
5. Xu, A. W. Chem. Lett. 2002, 982-983.
6. Xu, A. W. J. Phys. Chem. B 2002, 106, 11713-11715.
7. Xu, A. W. Chem. Lett. 2002, 878-879.
8. Xu, A. W.; Cai, Y. P.; Zhang, L. Z.; Yu, J. C. Adv. Mater. 2002, 14, 1064-
1068.
9. Xu, A. W.; Yu, J. C.; Cai, Y. P.; Zhang, H. X.; Zhang, L. Z. Chem. Commun.
2002, 1614-1615.
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FROM 162.105.51.*